G123002015 standard test method for evaluating stress corrosion cracking of stainless alloys with different nickel content in boiling acidified sodium chloride solution ubend specimens nickel content. Aisi 316l urea grade ug stainless steel scrubber lining was. A general definition of the phenomenon is that scc is the fracture of a material by the simultaneous action of a tensile stress and a corrosive environment. Standard recommended practice austenitic stainless steels and. The results of the study showed the detrimental effects of. Stress corrosion cracking of duplex stainless steels. Resistance to stress corrosion cracking is the most obvious advantage of the ferritic stainless steels. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. The study was based on the proposition that the resistance to stress corrosion cracking develops from grain boundary triple junctions with a resistant grain boundary i. Stress corrosion cracking of an austenitic stainless steel. Standard recommended practice austenitic stainless steels.
Figures 2,3,4 and 5 show the scc behaviour of type 304 austenitic stainless steel in dilute h 2 so 4 and expressed in terms of percentage elongation to fracture and in terms of reduction in cross sectional area. Irradiationinduced stress corrosion cracking of austenitic. Stress corrosion cracking issues in syngas plants that may. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stress corrosion cracking scc of duplex stainless steel. This paper discusses various cases of scc and stress induced cracking sic that normally occur with austenitic stainless steel in fertilizer plants and describes three case studies. In urea plant third stage intercooler of co2 compressor heat exchanger made of type ss304l stainless steel at a national fertilizer plant about 50 numbers of. Ductile iron has been used for valves in ammonia plants. In all cases, stress corrosion cracking was the failure mode by the action of. However, since 1997 several cases of scc have been discovered in the stainless steel components in pressurized water reactors pwr, which raises the concerns of life. External chloride stress corrosion cracking ecscc is a specific form of cui that occurs in austenitic stainless steels 300 series ss. Chloride stress corrosion cracking in austenitic stainless steel, health safety executive. Most of those who own solid stainless steel equipment operating in the cui temperature range are likely to experience ecscc at some point. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors.
Also, large areas of cathodic metal, such as titanium, stainless alloy. Stress corrosion cracking scc of austenitic stainless. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. In case 2, a heat exchanger shell failed during a hydrotest in a fertilizer plant. A phenomenon that regularly plagues the standard austenitic stainless steels of type aisi 304316 is stress corrosion cracking scc. Some of the typical forms of corrosion that occur in urea plant include. Tackling corrosion in urea processes stainless steel world. Aisi304l, 316l, or 321 may fail due to pitting corro sion or stress corrosion cracking depending on temper. Material selection for nitrogen based fertilizers plants 1. Welding may worsen the stress corrosion cracking susceptibility of the material. The benefits of n to scc resistance of dss are provided.
Chloride stress corrosion cracking in austenitic stainless. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. Effects of phosphorus and nitrogen on stress corrosion. Use of stainless steel ss lined carbon steel vessels in hp synthesis section and leak detection units 1, 2 can help mitigate the impact of chemicals on the process unit. Corrosion of metals by liquid fertilizer solutions corrosion. Chloride stress corrosion involves selective attack of a metal along its grain boundaries.
The higher nickel and molybdenum content in this grade allows it to demonstrate better overall corrosion resistant properties than 304, especially with regard to pitting and crevice corrosion in chloride environments. Corrosion and stress corrosion cracking in supercritical. Aisi 316l urea grade ug stainless steel scrubber lining was showed severe damage. In this study the influence of operating conditions such as chloride concentration, temperature on stress corrosion cracking of austenitic stainless steel will be investigated. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Chloride stress corrosion cracking is the most likely life limiting failure with austenitic stainless steel tubing. Sulfur in feed gas in chemical and petrochemical plants led to formation of polythionic acid h 2 s x o 6, x 25, which aside from moisture also induced intergranular stress corrosion cracking in austenitic stainless steels 46, 47. Stress corrosion cracking of an austenitic stainless steel in nitrite. Stress corrosion cracking behaviour of gas tungsten arc. Stress corrosion cracking of austenitic stainless steels. Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially stress corrosion cracking of austenitic stainless steel. Tensile stresses, both residual and applied, are usually present in cold equipment. In this articles described how to developed scc in austenite steel in.
The general pattern of the observed failures indicates that as nuclear plants age and fluence. In the completemix fertilizer solutions, only the chromiumnickel stainless steels were not attacked while aluminum, carbon steel, and three chromium stainless steels were attacked. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. This acid produces corrosive effect for stainless steel. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Mechanical properties and fracture morphology evolutions of the 304l asss were studied as a function of temperature through slow speed tensile tester and scanning electron microscopy sem. Conditions when plants are shut down must also be considered, as the condensates which are then formed can develop conditions that leads to both stress corrosion cracking scc and pitting. Stress corrosion cracking scc of austenitic stainless and. Pdf stress corrosion cracking of an austenitic stainless steel in. It also covers methods for detecting corrosion and investigating corrosionrelated failure, together with guidelines for improving corrosion protection of steels. Selection of material is vital at design stage itself. Phosphate industries use bulk amount of concentration h 2 so 4 during production of phosphate fertilizers.
Effect of temperature on the stress corrosion cracking of. Austenitic stainless steel is a more complex m aterial because the addition of nickel. Use of stainless steel ss lined carbon steel vessels in hp synthesis section and leak detection units 1, 2 can help mitigate the impact of chemicals on. Corrosion behavior of austenitic stainless steel in.
Grain boundary control for improved intergranular stress. Carbon steels in anhydrous ammonia service can suffer from stress. The study results have shown that in the natural environments containing aqueous solutions of sodium chloride nacl, the use of austenitic stainless steel containing chromium, nickel, molybdenum and titanium aisi 316ti is advised. In austenitic stainless steel, the main forms of corrosion are pitting and stress corrosion cracking caused by chlorides. The temperature of the column in the region of the cracking is approximately 70c 158f. Corrosion of austenitic stainless steels 1st edition. This paper discusses various cases of scc and stress induced crackingsic that normally occur with austenitic stainless steel in. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Abstract a phenomenon that regularly plagues the standard austenitic stainless steels of type aisi 304316 is stresscorrosion cracking scc. The chloride stresscorrosion cracking behavior of stainless. Failures of austenitic stainless steel components during storinis. Study of corrosion and corrosion protection of stainless. Severe stress corrosion cracking was observed in the csbp ltd, western australia 304l unlagged stainless steel absorber column of a nitric acid plant after 15 years of plant operation. Nickel and copper residuals lower resistance of these steels to stress corosion.
Stress corrosion cracking of stainless steels springerlink. Roy, examination committee chair associate professor of mechanical engineering university of nevada, las vegas the susceptibility of alloy ep823 to stress corrosion cracking has been evaluated. Type 439 with 1820% cr resists chloride stresscorrosion cracking. Heat exchangers are used in nuclear power plants and marine vehicles which are intended to operate in chloride rich offshore environment. Stress corrosion cracking of austenitic stainless steel weldments. An extensive study was undertaken to develope a steel resistant to stress corrosion cracking. Ferritic steels resist chloride and caustic stress corrosion cracking very well. The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic. Comparative corrosion study of austenitic aisi 304l and. Ammonium nitrateurea solution, used as fertilizer, and compared with the corrosion resistance results obtained in 3% aqueous solution of sodium chloride nacl.
Corrosion control in fertilizer industry training duration. Stress corrosion cracking resistance of martensitic. Most of those who own solid stainless steel equipment operating in the cui temperature range are likely to. Comparative corrosion study of austenitic aisi 304l and 316ti. Stress corrosion crack initiation in machined type 316l. A phenomenon that regularly plagues the standard austenitic stainless steels of type aisi 304316 is stresscorrosion cracking scc. Stress corrosion cracking of highpressure scrubber in urea plant. This comprehensive study covers all types of corrosion of austenitic stainless steel. Stress corrosion cracking, stainless steel, chloride. Austenitic stainless steels are less resistant to cyclic oxidation than are ferritic grades because their greater thermal expansion coefficient tends to cause the protective oxide coating to spall. Chlorideinduced stress corrosion cracking scc is one of the failure modes of stainless steels. Stress corrosion cracking in co2 compressor intercooler ijert. In applications demanding high resistance to stress corrosion cracking scc we recommend the duplex austeniticferritic steel sandvik saf 2304. Its atmospheric corrosion resistance is adequate for functional uses, so applications of this type of steel include automobile exhaust equipment, radiator tanks, catalytic reactors, containerization and dry fertilizer trunks.
In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r. A slow strain rate tensile ssrt test was carried out to investigate the stress corrosion cracking scc behavior of the sensitized 304l austenitic stainless steels asss in alkaline solution 0. This recapitulation of experiences with stress corrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades.
Highly alloyed austenitic stainless steels s32654, s31254, and n08028, and duplex grades s32750 and s31803 possess much improved resistance to scc compared with s30400 and s31600 steels. Stress corrosion cracking resistance of martensitic stainless. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Pitts, chloride stress corrosion cracking in austenitic stainless steel, health. Stress corrosion cracking of an austenitic stainless steel in.
External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Polythionic acid is another environment, which causes scc in austenitic stainless steels. These past few years, a limited number of cases of intergranular stress corrosion cracking igscc were detected in cold worked areas of non sensitized austenitic stainless steel. Austenitic stainless steels are widely used in nuclear power plants because their high resistance to stress corrosion cracking scc in high temperature water environment. Stress corrosion cracking resistance of martensitic stainless steels for transmutation applications by phani p. Prevention of external chloride stress corrosion cracking of. Type 439 with 1820% cr resists chloride stress corrosion cracking. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Stainless steel 316l bolts general properties alloy 316316l is molybdenumbearing austenitic stainless steel.
General corrosion and stress corrosion cracking scc susceptibility of an oxide dispersion strengthened ods austenitic 310 310ods steel in supercritical water scw are studied by weight. Prevention of external chloride stress corrosion cracking. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Stress corrosion cracking of austenitic stainless steel in fertilizer. The cracking was found when rust stainingleaks were observed. This paper discusses various cases of scc and stress induced crackingsic that normally occur with austenitic stainless steel in fertilizer plants and describes three case studies. Stress corrosion cracking ciscc corrosion fatigue caustic stress corrosion cracking.
Sensitization and testing for intergranular corrosion. They can experience stress corrosion crack ing scc if used in an environment to which they have insufficient corrosion resistance. Deterioration by clscc can lead to failures that have the potential to release. Stress corrosion cracking of austenitic stainless steels in.
Stress corrosion cracking scc of austenitic stainless steel weld metal. Stainless steel is major supporting metal for completion of several processing operational works. Austenitic stainless steels ass are widespread in primary circuits of pwr plants because of their good resistance to general corrosion at elevated temperature. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. Applications of fracture mechanics in stress corrosion cracking and introduction to. Chlorideinduced stresscorrosion cracking scc is one of the failure modes of stainless steels. Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially. This paper discusses various cases of scc and stress induced crackingsic that normally occur with austenitic stainless steel in fertilizer plants and describes. Chloride stress corrosion cracking inspectioneering. It develops corrosion cell on the surface of base metal and it changes its internal morphology as well as physical, chemical, mechanical properties. The final, definitive version of this document can be found online at. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. It develops corrosion cell on the surface of base metal and it changes its internal morphology as well as physical, chemical. Corrosion resistance of ferritic stainless steels total.
Service tests are being considered on carbon steel and some of the stainless steels that had satisfactory corrosion resistance in the laboratory tests. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Successful use of stainless steels in nitrogenbased fertilizer plants. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Material selection for nitrogen based fertilizers plants. Stress corrosion cracking of steel in liquefied ammonia. Results revealed existence of chloride assisted stress corrosion cracking. When questioned as to which grades of stainless steels andor duplexes mr. Nace conference paper 03523 stress corrosion cracking of austenitic stainless steel in fertilizer plants nace conference paper 02439 external scc phenomena of austenitic stainless steel in urea plants thomas eun. The similarities and differences in the stress corrosion cracking response of ferritic and austenitic stainless steels in chloride solutions will be examined. Irradiationinduced stress corrosion cracking of austenitic stainless steels.
Chloride stress corrosion cracking in austenitic stainless steel. As a standard, only safurex uns s32906, a proprietary superduplex stainless steel, is employed as the material of construction for all wetted parts in the synthesis section. Nuregcr7170 assessment of stress corrosion cracking. The relative superiority of duplex stainless steels dss over austenitic grades with regards to stress corrosion cracking scc is discussed. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Metallurgical influences on stress corrosion cracking. Stress corrosion cracking of austenitic stainless steel in. Astm g123 002015 standard test method for evaluating. G123002015 standard test method for evaluating stresscorrosion cracking of stainless alloys with different nickel content in boiling acidified sodium chloride solution u.
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